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Abstract
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Electrochemical oxidation of hydroquinone and catechols has been studied in the presence of triphenylphosphine (3) as a nucleophile in water/acetonitrile (40/60) solutions using cyclic voltammetry and controlled-potential coulometry. The results indicate that quinones derived from oxidation of hydroquinone or catechols, participate in a conjugate addition reaction with triphenylphosphine (3) via an EC mechanism, converting them to corresponding organophosphorus derivatives. In this work, we prepared C-phosphoniumquinol betaine compounds in good yields using a controlled-potential electrochemical
oxidation at a carbon electrode in a divided cell.
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