31 شهریور 1400
سيدعبداللطيف هاشمي فرد

سیدعبداللطیف هاشمی فرد

مرتبه علمی: دانشیار
نشانی: دانشکده مهندسی نفت، گاز و پتروشیمی - گروه مهندسی شیمی
تحصیلات: دکترای تخصصی / مهندسی شیمی
تلفن: 09177755574
دانشکده: دانشکده مهندسی نفت، گاز و پتروشیمی

مشخصات پژوهش

عنوان Preparation and characterization of PVDF-montmorillonite mixed matrix hollow fiber membrane for gas–liquid contacting process
نوع پژوهش مقالات در نشریات
کلیدواژه‌ها
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مجله CHEMICAL ENGINEERING RESEARCH & DESIGN
شناسه DOI
پژوهشگران M Rezaei (نفر اول) ، احمد فائوزی اسماعیل (نفر دوم) ، سیدعبداللطیف هاشمی فرد (نفر سوم) ، T. Matsuura (نفر چهارم)

چکیده

Porous PVDF-hydrophobic montmorillonite (MMT) mixed matrix membranes (MMMs) were fabricated via wet spinning method and used in membrane gas absorption process. The effects of hydrophobic MMT nano-clay loadings (1, 3 and 5wt% of polymer) on the structure and performance were investigated. The fabricated membranes showed both finger-like and sponge-like structure with an increase in the length of finger-like pores in their cross-section, which resulted in higher permeability and lower mass transfer resistance compared to plain PVDF membrane. Also, significant improvements for surface hydrophobicity, critical entry pressure of water and porosity with the addition of filler were observed. The CO2 absorption test was conducted through the gas–liquid membrane contactor and demonstrated a significant improvement in the CO2 flux with MMT loading and the membrane with 5wt% MMT presented highest performance. For example, at the liquid water velocity of 0.5ms?1, CO2 flux of the MMM with 5wt% MMT of 9.73×10?4 molm?2 s?1 was approximately 56% higher than the PVDF membrane without nano-filler. In conclusion, MMMs with improved absorption properties can be a promising candidate for CO2 absorption and separation processes through membrane contactors.