09 فروردین 1403
علي محمد صنعتي

علی محمد صنعتی

مرتبه علمی: استادیار
نشانی: پژوهشکده خلیج فارس - گروه محیط زیست
تحصیلات: دکترای تخصصی / محیط زیست - آلودگی
تلفن: 07731222231
دانشکده: پژوهشکده خلیج فارس

مشخصات پژوهش

عنوان
سنتز و کاربرد کاتالیست فلزی آلی، بر پایه FSM-16 برای واکنش چند جزیی
نوع پژوهش مقالات در همایش ها
کلیدواژه‌ها
organometallic catalyst, FSM-16و reactionو 1, 3-diaza-2,4-cyclopentadiene
پژوهشگران مریم حجامی (نفر اول) ، علی محمد صنعتی (نفر دوم) ، فاطمه غلامیان (نفر سوم)

چکیده

Classification of ordered mesoporous materials M41S into three groups of hexagonal phase included MCM-41 and FSM-16, cubic phase named MCM-48 and unstable lamellar phase recognized MCM-50 reported in literature.1 FSM-16, due to their thicker pore walls, in comparison with MCM-41 has a higher thermal and hydrothermal stability. For this reasons, we focused on FSM- 16 which act as hosts to immobilize a new metal complexes and synthesis a new catalyst.2 1, 3-diaza-2,4-cyclopentadiene compounds which known as imidazole, have two N heteroatom.3 These compounds have wide utilities in various fields for example in pharmacy, biological systems also in chemistry such as use as ionic liquids for synthesis of organometallic catalysis and N-heterocyclic carbenes.4 In this way, for the development of new practical method, we designed a new catalyst system. This organometallic catalyst, based on FSM-16, named as FSM-16@CPTMS-Rh-Ni and applied for multi component reaction such as synthesis of 2,4,5-triaryl-1H-imidazoles and 1,2,4,5-tetrasubstituted imidazoles (Scheme 1).