10 فروردین 1403

محمد عباسی

مرتبه علمی: دانشیار
نشانی: دانشکده علوم و فناوری نانو و زیستی - گروه شیمی
تحصیلات: دکترای تخصصی / شیمی آلی
تلفن: 09173096425
دانشکده: دانشکده علوم و فناوری نانو و زیستی

مشخصات پژوهش

عنوان Europhtal: An industrial cobalt phthalocyanine complex as the efficient catalyst for synthesis of thioamides by one-pot reaction of mercaptans and amines
نوع پژوهش مقالات در نشریات
کلیدواژه‌ها
amines, Europhtal catalyst (8020), organometallic catalysts, Thioamides, thiols
مجله APPLIED ORGANOMETALLIC CHEMISTRY
شناسه DOI 10.1002/aoc.6709
پژوهشگران ناصر زرین درخت (نفر اول) ، محمد عباسی (نفر دوم) ، نجمه نوروزی (نفر سوم)

چکیده

The potential of industrial cobalt phthalocyanines in the synthesis of thioamides is reported. A mixture of an industrial sulfonated cobalt phthalocyanines known as Co[(SO3Na)2,3Pc] (Europhtal catalyst additive 8020) is introduced as an efficient catalyst capable of converting benzyl thiols to synthetically valuable thioamides by reaction with amines and DMSO. In this procedure, different primary and secondary amines also heterocyclic amines were successfully converted into benzothioamides in high yields. This simple, one-pot three-component conversion method is scalable and provides efficient and practical route to the synthesis of diverse benzothioamides.