10 فروردین 1403
مسعود مفرحي

مسعود مفرحی

مرتبه علمی: استاد
نشانی: دانشکده مهندسی نفت، گاز و پتروشیمی - گروه مهندسی شیمی
تحصیلات: دکترای تخصصی / مهندسی شیمی
تلفن: 07331222613
دانشکده: دانشکده مهندسی نفت، گاز و پتروشیمی

مشخصات پژوهش

عنوان Correlation and prediction of solubility of hydrogen in alkenes and its dissolution properties
نوع پژوهش مقالات در نشریات
کلیدواژه‌ها
PR EoS · Solubility · Henry’s constant · Thermodynamic properties · Hydrogen · Alkene
مجله Applied Petrochemical Research
شناسه DOI 10.1007/s13203-020-00260-w
پژوهشگران محمد جمالی (نفر اول) ، امیرعباس ایزدپناه (نفر دوم) ، مسعود مفرحی (نفر سوم)

چکیده

In this work, solubility of hydrogen in some alkenes was investigated at diferent temperatures and pressures. Solubility values were calculated using the Peng–Robinson equation of state. Binary interaction parameters were calculated using ftting the equation of state on experimental data, Group contribution method and Moysan correlations and total average absolute deviation for these methods was 3.90, 17.60 and 13.62, respectively. Because hydrogen solubility in Alkenes is low, Henry’s law for these solutions were investigated, too. Results of calculation showed with increasing temperature, Henry’s constant was decreased. The temperature dependency of Henry’s constants of hydrogen in ethylene and propylene was higher than to other alkenes. In addition, using Van’t Hof equation, the thermodynamic parameters for dissolution of hydrogen in various alkenes were calculated. Results indicated that the dissolution of hydrogen was spontaneous and endothermic. The total average of dissolution enthalpy (ΔH◦) and Gibbs free energy (ΔG◦) for these systems was 3.867 kJ/mol and 6.361 kJ/mol, respectively. But dissolution of hydrogen in almost of alkenes was not an entropy-driven process.