In the present study, thin film composite (TFC) forward osmosis (FO)
membranes with polycarbonate (PC (and polyether sulfone (PES) as substrates
were fabricated to investigate the impact of the structural parameters of substrate
on the performance of the membranes. Firstly, the substrates were prepared
by Loeb-Sourirajan method. Characterization techniques including
FESEM, contact angle measurement, pure water flux, gas permeability test,
and tensile test were applied to investigate the properties of the substrates.
After preparing suitable substrates, active layers were fabricated via interfacial
polymerization (IP) technique. The performance and characterization test
showed that PC is a relatively hydrophilic polymer with a good property for
using as a substrate of FO TFC membrane but as the result of gas permeability
test show, this membrane has large surface pore size in comparison with PES
membrane. Mean pore size of PC and PES membrane is 378 and 139 nm,
respectively. Also, the results show that the effective surface porosity of PC
(285, 1/m) is more than PES (213, 1/m) substrate.