In this study, diethylene glycol adsorbent (DEG) was used to dehumidify the gas. For this purpose, a hollow fiber membrane contactor made of polyvinyl chloride (PVC) modified with silicone rubber (PDMS) and calcium carbonate nanoparticles (CaCo_3) was fabricated. The effect of surface modification with silicone rubber in the presence of calcium carbonate nanoparticles, relative humidity percentage of incoming air, different flow rates of gas and liquid, in water vapor adsorption operation was investigated.