05 بهمن 1403
عبدالكريم زارع

عبدالکریم زارع

مرتبه علمی: استاد
نشانی: دانشکده علوم و فناوری نانو و زیستی - گروه شیمی
تحصیلات: دکترای تخصصی / شیمی آلی
تلفن: 07731222717
دانشکده: دانشکده علوم و فناوری نانو و زیستی

مشخصات پژوهش

عنوان Design and characterization of nano-silica-bonded 3-n-propyl-1-sulfonic acid imidazolium chloride {nano-SB-[PSIM]Cl} as a novel, heterogeneous and reusable catalyst for the condensation of arylaldehydes with β-naphthol and alkyl carbamates
نوع پژوهش مقالات در نشریات
کلیدواژه‌ها
Nano-silica-bonded 3-n-propyl-1-sulfonic acid imidazolium chloride {nano-SB-[PSIM]Cl}; Silica-supported Brønsted acidic ionic liquid; Arylaldehyde; 2-Naphthol; Carbamatoalkyl naphthol
مجله RESEARCH ON CHEMICAL INTERMEDIATES
شناسه DOI 10.1007/s11164-015-2154-7
پژوهشگران عبدالکریم زارع (نفر اول) ، ماریا معراج الدین (نفر دوم) ، احمد رضا موسوی زارع (نفر سوم) ، محمود زارعی (نفر چهارم) ، محمد حسن بیضاوی (نفر پنجم) ، محمد علی زلفی گل (نفر ششم به بعد)

چکیده

In this research, nano-silica-bonded 3-n-propyl-1-sulfonic acid imidazolium chloride {nano-SB-[PSIM]Cl} as a new and efficient Brønsted acidic ionic liquid supported on silica has been synthesized, and characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, thermogravimetric, differential thermal gravimetric, X-ray diffraction, and energy-dispersive X-ray spectroscopy spectra. The presented silica-supported ionic liquid has been applied as a highly effective, heterogeneous, easy regenerable, and reusable catalytic system for the solvent-free condensation of arylaldehydes with b-naphthol and alkyl carbamates leading to a-carbamatoalkyl-b-naphthols. Once the nanocatalyst was regenerated and reused, no significant loss of its activity was observed.