January 24, 2025
Abdolkarim Zare

Abdolkarim Zare

Academic Rank: Professor
Address: Department of Chemistry, Faculty of Nano and Bio Science and Technology
Degree: Ph.D in Organic chemistry
Phone: 07731222717
Faculty: Faculty of Nano and Biotechnology

Research

Title Fabrication of a new magnetic nanocatalyst and its application for the effectual construction of pyrimido[4,5-b]quinolines
Type Article
Keywords
Magnetic nanocatalyst; [Fe3O4@SiO2@RNMe2-SO3H][CF3CO2]; 6-Amino-1,3-dimethyluracil; Pyrimido[4,5- b]quinoline
Journal Iranian Journal of Catalysis
DOI 10.57647/j.ijc.2024.1404.43
Researchers Abdolkarim Zare (First researcher) , Marziyeh Barzegar (Second researcher) , Ahmad Reza Moosavi-Zare (Third researcher)

Abstract

A new magnetic nanocatalyst, namely [Fe3O4@SiO2@RNMe2-SO3H][CF3CO2] (FSRNSC), was fabricated, and characterized using FT-IR, EDS (energy-dispersive X-ray spectroscopy), elemental mapping, FE-SEM (field-emission scanning electron microscopy), XRD (X-ray diffraction), VSM (vibrating-sample magnetometry), TG (thermogravimetric) and DTG (differential thermogravimetric) analyses. It was utilized as a highly effectual and magnetically recoverable catalyst for the construction of pyrimido[4,5-b]quinolines (12 examples) in high yields (15−50 min) and short times (88−96%). The synthesis was performed through the one-pot, three-component reaction of aryl aldehydes, dimedone, and 6-amino-1,3-dimethyluracil in the absence of solvent.