January 24, 2025
Abdolkarim Zare

Abdolkarim Zare

Academic Rank: Professor
Address: Department of Chemistry, Faculty of Nano and Bio Science and Technology
Degree: Ph.D in Organic chemistry
Phone: 07731222717
Faculty: Faculty of Nano and Biotechnology

Research

Title Ionic liquid 1,3-disulfonic acid imidazolium hydrogen sulfate: a novel and highly efficient catalyst for the preparation of 1-carbamatoalkyl-2-naphthols and 1-amidoalkyl-2-naphthols
Type Article
Keywords
Ionic liquid; 1,3-disulfonic acid imidazolium hydrogen sulfate; 1-carbamatoalkyl-2-naphthols; 1-amidoalkyl-2-naphthols; solvent-free
Journal RSC Advances
DOI 10.1039/C2RA20679J
Researchers Abdolkarim Zare (First researcher) , Tahereh Yousofi (Second researcher) , Ahmad Reza Moosavi-Zare (Third researcher)

Abstract

In this work, a novel ionic liquid, 1,3-disulfonic acid imidazolium hydrogen sulfate {[Dsim]HSO4}, with a Brønsted acidic property, is synthesized, and used as a highly efficient, green, recyclable and homogeneous catalyst for the preparation of 1-carbamatoalkyl-2-naphthols and 1-amidoalkyl-2-naphthols under solvent-free and relatively mild conditions. The one-pot multi-component condensation of b-naphthol with arylaldehydes and alkyl carbamates or amides affords the title compounds in high yields and in short reaction times.