Nano-[SiO2@R-Im-SO3H][CF3COO]: an effectual catalyst for the production of bis-coumarins and N,N′-alkylidene bisamides, By Abdolkarim Zare

Research

Title	Nano-[SiO2@R-Im-SO3H][CF3COO]: an effectual catalyst for the production of bis-coumarins and N,N′-alkylidene bisamides
Type	Article
Keywords	Nano-[SiO2@R-Im-SO3H][CF3COO] (NSRISC), Organic-inorganic hybrid nanomaterial, Solvent-free, Bis-coumarin, N,N′-Alkylidene bisamide
Journal	Iranian Journal of Catalysis
DOI	10.30495/ijc.2022.689835
Researchers	Jaleh Atashrooz (First researcher) , Abdolkarim Zare (Second researcher)

Abstract

A novel organic-inorganic hybrid nanomaterial namely nano-[SiO2@R-Im-SO3H][CF3COO] (NSRISC) was synthesized, and characterized using FT-IR, EDS, FE-SEM, TGA and XRD analyses. Thereafter, the solvent-free production of bis-coumarins (from aryl aldehydes and 4-hydroxycoumarin) and N,Nâ²-alkylidene bisamides (from aryl aldehydes and benzamide) was catalyzed by NSRISC. Bis-coumarins were produced in 86-97% at 100 ºC, and bisamides were obtained in 87-97% at 105 ºC. The reaction times were 15-30 min for both kinds of compounds.