[Fe3O4@SiO2@Si-pr-NMe2-et-NHMe2] [FeCl4] [HSO4] as a Novel and Effective Catalyst for the Fabrication of 14-Aryl-14Hdibenzo[ a,j]xanthenes, By Abdolkarim Zare

Research

Title	[Fe3O4@SiO2@Si-pr-NMe2-et-NHMe2] [FeCl4] [HSO4] as a Novel and Effective Catalyst for the Fabrication of 14-Aryl-14Hdibenzo[ a,j]xanthenes
Type	Article
Keywords	[Fe3O4@SiO2@Si-pr-NMe2-et-NHMe2] [FeCl4] [HSO4]; Solvent-free; Magnetic nanomaterial Nanocatalyst;14-Aryl-14H-dibenzo[a,j]xanthene
Journal	advanced journal of chemistry-section a
DOI	10.48309/ajca.2025.506230.1785
Researchers	Amin Rasouli (First researcher) , Abdolkarim Zare (Second researcher) , Mohammad Hosain Naderi-Zadeh (Third researcher)

Abstract

A new magnetic nanomaterial namely [Fe3O4@SiO2@Si-pr-NMe2-et-NHMe2][FeCl4] [HSO4] (FSPNFH) was constructed, and characterized using EDS, elemental mapping, FT-IR, FE-SEM, VSM, XRD, and TG analyses. Therefore, FSPNFH was exploited as a magnetically recoverable catalyst for the fabrication of 14-aryl-14H-dibenzo[a,j]xanthenes via the condensation of aryl aldehydes (1 eq.) with 2-naphthol (2 eq.) under solvent-free conditions. The xanthene derivatives were obtained in high yields (89-97%) and short times (15-30 min). FSPNFH was reused twice without significant diminishing in its activity.