02 دی 1403

لیلا مفتون آزاد

مرتبه علمی: استادیار
نشانی: دانشکده علوم و فناوری نانو و زیستی - گروه شیمی
تحصیلات: شیمی
تلفن:
دانشکده: دانشکده علوم و فناوری نانو و زیستی

مشخصات پژوهش

عنوان Equation of State for Alkaline Earth Metals: Prediction from Boiling Point Constants
نوع پژوهش مقالات در نشریات
کلیدواژه‌ها
Correlation, Equation of State, Liquid Density, Molten Alkaline Earth Metals
مجله JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
شناسه DOI https://doi.org/10.1252/jcej.37.871
پژوهشگران حسین اسلامی (نفر اول) ، لیلا مفتون آزاد (نفر دوم) ، علی بوشهری (نفر سوم)

چکیده

A statistical-mechanical analytical equation of state has been employed successfully to molten alkaline earth metals. The temperature-dependent parameters of the equation of state have been calculated using our previously reported corresponding-states correlation based on the normal boiling point parameters as the scaling constants. It is shown that knowledge of just normal boiling temperature and the liquid density at a normal boiling point are sufficient to predict the equation of state of magnesium, calcium, stroncium, and barium from the melting points up to several hundred degrees above their boiling points. A comparison of calculated saturated liquid densities of these metals with experimental ones shows that our predicted results are within a 5% difference of experimental ones.