December 22, 2024

Mohammad Abbasi

Academic Rank: Associate professor
Address:
Degree: Ph.D in organic chemistry
Phone: 09173096425
Faculty: Faculty of Nano and Biotechnology

Research

Title The use of Cr (CO)6 as an alternative CO source in Pd catalyzed CN bond formation: Synthesis of benzamides
Type Article
Keywords
Journal APPLIED ORGANOMETALLIC CHEMISTRY
DOI
Researchers Najmeh Nowrouzi (Second researcher) , Mohammad Abbasi (Third researcher)

Abstract

An efficient strategy for the synthesis of benzamides from acetamides and aryl iodides using 1 mol% Pd (OAc)2 as catalyst and Cr (CO)6 as CO?precursor is described. This new synthetic methodology displays high functional group tolerance on both substrates and avoids the need for ligands, reducing agents, or other additives. The corresponding products were obtained in good to excellent yields at atmospheric pressure under mild reaction conditions.