محمدهاشم صدق کردار

Highly stabilized mesoporous core–shell-structured oxygen carriers (OCs) were fabricated by a repetitive coating process of alumina supports using the mesopore-forming surfactant assembly method. The wet coating strategy, along with the sol–gel process, was used for the synthesis of mesoporous material-shelled OCs with various shell compositions (i.e., zirconia, titania). The cyclic performance of the synthesized OCs during chemical looping combustion (CLC) was investigated in a thermogravimetric analyzer (TGA). The mesoporous-shelled OCs demonstrated significantly better performance compared to the OCs without mesoporous shells. The synthesized OCs with a mesoporous zirconia/titania shell reveal a unique oxygen capacity of 100% based on active metal oxide for supported NiO and Fe2O3. Also, the synthesized OCs showed no activity loss after 10 cycles. This was attributed to the exceptional core–shell coating strategy, in which the thermally stable mesoporous Zr/Ti layers prevent the sintering and over-reaction of the active metal oxide crystals with the alumina support.