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Abstract
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Grain growth behaviour of the nanocrystalline CoAl intermetallic compound synthesized by
mechanical alloying has been studied by isothermal annealing at different temperatures and durations. X-ray
diffraction method was employed to investigate structural evolutions during mechanical alloying and annealing
processes. The disordered CoAl phase with the grain size of about 6 nm was formed via a gradual reaction
during mechanical alloying. The results of isothermal annealing showed that the grain growth behaviour can
be explained by the parabolic grain growth law. The grains were at nanometric scale after isothermal annealing
up to 0?7 Tm. The grain growth exponent remained constant above 873 K indicating that grain growth
mechanism does not change at high temperatures. The calculated activation energy indicated that the grain
growth mechanism in the disordered CoAl phase at high temperatures was diffusing Co and Al atoms in two
separate sublattices. Furthermore, an equation has been suggested to describe the grain growth kinetics of
nanocrystalline CoAl under isothermal annealing at temperatures above 873 K (T/Tm ? 0?5).
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