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Title
Synthesis of new allylidene amino phenolcontaining Schiff bases and metal complex formation using trimethinium salts
Type Article
Keywords
trimethinium salts, Vinamidinium salt, Schiff bases
Abstract
An efficient route for the synthesis of novel Schiff bases from the condensation reaction of 2-substituted 1,3-bis(dimethylamino)-trimethinium salts with diverse aminophenols in the presence of triethylamine in EtOH at reflux is described. Complexes of transition metals with Schiff base ligand (L) 3c, having the donor atom set N2O2, were studied. The ultraviolet spectral behavior of the complexes in DMSO was investigated and the lmax of these compounds was examined. The structure of the new compounds was confirmed based on their spectral data from IR, 1H NMR and 13C NMR, mass spectra, and elemental analysis.
Researchers Abdolmohammad Mehranpour (Second researcher)