Research Info

Home \Synthesis of imidazolium ...
Title
Synthesis of imidazolium ionic liquid immobilized on magnetic mesoporous silica: A sorbent material in a green micro-solid phase extraction of multiclass pesticides in water
Type Article
Keywords
Ionic Liquid, Mesoporous Silica nanoparticles, solid phase micro extraction, chromatography
Abstract
In this study, we synthesized an imidazolium ionic liquid immobilized on magnetic mesoporous silica (IL-MMS) and evaluated its performance as a sorbent material for a green micro-solid phase extraction (μ-SPE) of multiclass pesticides in water. The synthesized IL-MMS was characterized by various analytical techniques, including Fourier-transform infrared spectroscopy (FTIR), Brunauer–Emmett–Teller (BET) and Barrett–Joyner–Halenda (BJH) analyses (N2 adsorption/desorption), Vibrating Sample Magnetometer (VSM), energy-dispersive spectroscopy (EDS) and Field emission scanning electron microscopy (FESEM). Our synthesized IL-MMS demonstrated excellent magnetic properties (31.5 emu/g), high surface area (1177.4 m2/g), proper pore size (⁓4.2 nm) and volume (1.80 cm3/g). Under optimized extraction conditions, the IL-MMS exhibited a high adsorption capacity for a variety of pesticides, including organophosphates, carbamates, and pyrethroids. The proposed μ-SPE method using IL-MMS showed good linearity (R2 > 0.99), low limits of detection (LODs) ranging from 0.04 to 1.63 ng/L, and suitable recovery rate was between 82.4% and 109.8% for different pesticides. In addition, the method also exhibited excellent reproducibility, with relative standard deviations (RSDs) of less than 8% for both intra and inter-day precision. In overall, the synthesized IL-MMS has proven to be a highly promising material for sorbent-based micro-solid phase extraction (μ-SPE) of multiclass pesticides in water. With its simple, efficient, and eco-friendly approach to pesticide analysis, this method shows great potential for future pesticide detection and monitoring efforts due to its sensitivity, accuracy, and adaptability to various environmental conditions.
Researchers Seyed Farnood Farzam (First researcher) , Farzaneh Shemirani (Second researcher) , Sadegh Karimi (Third researcher)