مشخصات پژوهش

خانه /One-pot, sequential ...
عنوان
One-pot, sequential four-component synthesis of benzo[c]pyrano[3,2-a]phenazine, bis-benzo[c]pyrano[3,2-a]phenazine and oxospiro benzo [c]pyrano[3,2-a]phenazine derivatives using 1,4-diazabicyclo[2.2.2]octane (DABCO) as an efcient and reusable solid base catalyst
نوع پژوهش مقالات در نشریات
کلیدواژه‌ها
ثبت نشده‌است!
چکیده
Abstract 1,4-Diazabicyclo[2.2.2]octane (DABCO) has been used as an ef?cient and reusable solid base catalyst for the one-pot, two-step, four-component synthesis of pyrano[3,2-a]phenazine derivatives by the condensation reaction of 2-hydroxy-1,4-naphthoquinone, 1,2-diamines, carbonyl compounds and alkylmalonates under conventional heating as well as microwave irradiation. This procedure has also been applied successfully for the synthesis of novel bis- benzo[c]pyrano[3,2-a]phenazine and oxospiro benzo[c]pyrano[3,2-a]phenazine derivatives. Using this procedure, all the products were obtained in good to excellent yields. The catalyst has been recovered and reused several times without any loss of reactivity.
پژوهشگران علیرضا حسنی نژاد (نفر اول)، مریم فیروزی (نفر دوم)