مشخصات پژوهش

خانه /N,N,N',N'-Tetramethyl-N,N'-bis
عنوان
N,N,N',N'-Tetramethyl-N,N'-bis(sulfo)ethane-1,2-Diaminium Mesylate as a Highly Effective and Dualfunctional Catalyst for the Synthesis of 1-Thioamidoalkyl-2-naphthols
نوع پژوهش مقالات در نشریات
کلیدواژه‌ها
N,N,N',N'-Tetramethyl-N,N'-bis(sulfo)ethane-1,2-diaminium mesylate ‎‎([TMBSED][Oms]2)‎; ‎Thioacetamide; 1-Thioamidoalkyl-2-naphthol; Multi-component ‎reaction; Dicationic ionic liquid; Dual-functional ‎catalyst‎
چکیده
N,N,N',N'-tetramethyl-N,N'-bis(sulfo)ethane-1,2-diaminium mesylate ‎‎([TMBSED][Oms]2) is ‎used as a highly efficient and dual-functional catalyst for the one-pot multi-component ‎condensation of 2-naphthol with arylaldehydes and thioacetamide under green, mild (70 °C), ‎and solvent-free conditions. In this reaction, 1-thioamidoalkyl-2-naphthols are produced in ‎high to excellent yields and in relatively short reaction times. In this reaction, products ‎are identified by analysis of its 1H NMR, 13C NMR, and FT-IR data.‎ Moreover, a plausible mechanism based on dual-functionality of the catalyst was proposed.
پژوهشگران نوید ایران نژاد قشلاقچایی (نفر اول)، عبدالکریم زارع (نفر دوم)، علیرضا بنایی (نفر سوم)، حمیده کاوه (نفر چهارم)، ناهید وراوی (نفر پنجم)
تاریخ انجام 1399-05-12