مشخصات پژوهش

A hybrid polymeric system containing carbon nanofillers with different geometrical dimensions is proposed for strategic applications, particularly for electrical properties. Two different carbon nanofillers including functionalized multiwalled carbon nanotubes (fCNTs) and functionalized graphene nanoplatelets (fGnPs) were added to thermoplastic polyurethane (TPU) to prepare single and hybrid nanofiller filled TPU through solution mixing. Sufficient exfoliation of the fGNPs in the single nanocomposites was confirmed by X-ray diffraction (XRD), while single filler and hybrid TPU nanocomposites containing fCNTs showed some re-aggregation of these nanofillers. Linear rheology together with scanning electron microscopy revealed a proper exfoliation and dispersion degree for fGnPs and fCNTs, respectively. We have shown that simultaneous addition of fCNTs-fGnPs in the form of a hybrid system into the TPU made a large surface area available and strong interfacial interactions were formed between the hybrid network and the TPU matrix. This in turn led to electrical, thermal and mechanical properties, which were superior to those predicted by the mixture law.