مشخصات پژوهش

خانه /Triethylamine-bonded sulfonic ...
عنوان
Triethylamine-bonded sulfonic acid ([Et 3N–SO 3H]Cl): a highly efficient and homogeneous catalyst for the condensation of 2-naphthol with arylaldehydes and amides (alkyl carbamates or thioamides)
نوع پژوهش مقالات در نشریات
کلیدواژه‌ها
Triethylamine-bonded sulfonic acid ([Et3N–SO3H]Cl, N,N-diethyl-N-sulfoethanammonium chloride); ionic liquid; 1-amidoalkyl-2-naphthol; 1-carbamatoalkyl-2-naphthol; 1-thioamidoalkyl-2- naphthol
چکیده
Ionic liquid triethylamine-bonded sulfonic acid ([Et3N–SO3H]Cl, N,N-diethyl-N-sulfoethanammonium chloride) is utilized as a highly efficient, inexpensive and homogeneous catalyst to promote the following one-pot multi-component organic transformations under solvent-free conditions: (i) the condensation of 2-naphthol with arylaldehydes and amides leading to 1-amidoalkyl-2-naphthols, (ii) the reaction of 2-naphthol with aromatic aldehydes and alkyl carbamates to produce 1-carbamatoalkyl-2-naphthols, and (iii) the condensation between 2-naphthol, arylaldehydes and thioamides leading to 1-thioamidoalkyl-2-naphthols. High yields, short reaction times, efficiency, generality, clean process, simple methodology, low cost, easy work-up, ease of preparation of the catalyst, and environmentally benign conditions are some advantages of the protocols.
پژوهشگران عبدالکریم زارع (نفر اول)، شایسته اکبرزاده (نفر دوم)، المیرا فروزانی (نفر سوم)، حمیده کاوه (نفر چهارم)، احمد رضا موسوی زارع (نفر پنجم)، علیرضا حسنی نژاد (نفر ششم به بعد)، محمد مخلصی (نفر ششم به بعد)، محمد حسن بیضاوی (نفر ششم به بعد)، محمد علی زلفی گل (نفر ششم به بعد)