مشخصات پژوهش

خانه /Rapid and Highly Selective ...
عنوان
Rapid and Highly Selective Epoxidation of Styrene by meta-Chloroperbenzoic Acid Catalyzed by Manganese Meso-tetrakis(Pentafluorophenyl)Porphyrin in the Presence of Tetrabutylammonium Acetate and Bromide
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چکیده
Epoxidation of styrene with m-CPBA in the presence of Mn(TPFPP)Cl was improved to high yield (98–100%) and excellent selectivity (100%) by using n-Bu4NOAc or n-Bu4NBr as co-catalysts in less than 5 min. Also comparison of co-catalytic activity of n-Bu4NOAc, n-Bu4NBr and imidazole in epoxidation of cis-stilbene and styrene was carried out at similar conditions.
پژوهشگران زهرا صولتی دالکی (نفر اول)، سید مجید هاشمی (نفر دوم)، لیلا ابراهیمی (نفر سوم)