مشخصات پژوهش

خانه /In situ generation of trityl ...
عنوان
In situ generation of trityl carbocation (Ph3C+) as a homogeneous organocatalyst for the efficient synthesis of 4,4'‐(arylmethylene)‐bis(3‐methyl‐1‐phenyl‐1H‐pyrazol‐5‐ol)s
نوع پژوهش مقالات در نشریات
کلیدواژه‌ها
Trityl chloride (Ph3CCl); Trityl carbocation (Ph3C+); 4,4'‐(Arylmethylene)‐bis(3‐methyl‐1‐phenyl‐1H‐pyrazol‐5‐ol); 3‐Methyl‐1‐phenyl‐1H‐pyrazol‐5(4H)‐one; Solvent‐free synthesis
چکیده
Trityl chloride (Ph3CCl) efficiently catalyzes the condensation of 3‐methyl‐1‐phenyl‐1H‐pyrazol‐5(4H)‐one and aromatic aldehydes under mild and solvent‐free conditions, affording 4,4'‐ (arylmethylene)‐bis(3‐methyl‐1‐phenyl‐1H‐ pyrazol‐5‐ol)s in high to excellent yields and in short reaction time. The presence of the requisite organocatalytic trityl carbocation (Ph3C+) species was confirmed by analysis of infred, 1H NMR, and ultra violet spectral data. A plausible mechanism was proposed for the reaction based on the observations and literature precedent.
پژوهشگران عبدالکریم زارع (نفر اول)، ماریا معراج الدین (نفر دوم)، احمد رضا موسوی زارع (نفر سوم)، محمود زارعی (نفر چهارم)