مشخصات پژوهش

خانه /Catalytic epoxidation of ...
عنوان
Catalytic epoxidation of cis-stilbene and naphthalene by tetra-n-butylammonium hydrogen monopersulfate in the presence of manganese(III) tetraarylporphyrins and various anionic co-catalysts
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چکیده
The epoxidation of cis-stilbene by n-Bu4NHSO5 was studied in the presence of two different manganese porphyrin complexes, [MnTPFPP(Cl) and MnTPP(Cl)], and various n-Bu4NX (X = OAc, F, Cl, Br, OCN, NO3, BF4). In general direct correlation was found between stereoselectivity of the epoxidation reaction and the nucleophilic properties of these anionic co-catalysts. Also epoxidation of naphthalene was carried out in high yield and good selectivity by n-Bu4NHSO5 in the presence of MnTPFPP(Cl) in association with n-Bu4NOAc or n-Bu4NF co-catalysts.
پژوهشگران زهرا صولتی دالکی (نفر اول)، سید مجید هاشمی (نفر دوم)، احمد کشاورز (نفر سوم)، عزت رفیعی (نفر چهارم)